At 25C, you conduct a titration of 20.00 mL of a 0.0400 M AgNO3 solution with a 0.050 M NaI solution within the following cell:
Saturated Calomel Electrode | Titration solution | Ag(s)
for the cell as writted, what is the voltage after the addition of 10.00 mL of the NaI sooution? The reduction potential for the saturated calomel electrode is E=0.241 V. The standard reduction potential for the reaction: Ag++e– ® Ag(s)
E0= 0.79993V. The solubility constant of AgI is Ksp=8.3×10-17
Note: the cell potential could be negative since the condditions are non-standard ones.
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